Severe and extreme surface charging on geosynchronous spacecraft is examined through the analysis of 16 years of data from particles detectors on-board the Los Alamos National Laboratory spacecraft. Analysis shows that high spacecraft frame potentials are correlated with 10 to 50 keV electron fluxes, especially when these fluxes exceed 1 × 108 cm−2 s−1 sr−1. Four criteria have been used to select severe environments: 1) large flux of electrons with energies above 10 keV, 2) large fluxes of electrons with energies below 50 keV and above 200 keV, 3) large flux of electrons with energies below 50 keV and low flux with energies above 200 keV, and 4) long periods of time with a spacecraft potential below – 5 kV. They occur preferentially during either geomagnetic storms or intense isolated substorms, during the declining phase of the solar cycle, during equinox seasons and close to midnight local time. The set of anomalies reported in Choi et al. (2011) is concomitant with a new database constructed from these events. The worst-case environments exceed the spacecraft design guidelines by up to a factor of 10 for energies below 10 keV. They are fitted with triple Maxwellian distributions in order to facilitate their use by spacecraft designers as alternative conditions for the assessment of worst-case surface charging.